Publications

110. Mader, E.A.; Larsen, A.S.; Mayer, J.M.
Hydrogen Atom Transfer from Iron(II)-tris[2,2'-bi(tetrahydropyrimidine)] to TEMPO: A Negative Enthalpy of Activation,
J. Am. Chem. Soc.   2004, 126, 8066-8067  
109. Soper, J.D.; Rhile, I.J.; DiPasquale, A.G.; Mayer, J.M.
Oxidation of TpOsIII(NH2Ph)Cl2 to TpOsIV(NHPh)Cl2 by O2,
Polyhedron  2004, 23, 323-329  
108. Bryant, J.R.; Matsuo, T.; Mayer, J.M.
Cumene Oxidation by cis-[RuIV(bpy)2(py)(O)]2+, Revisited,
Inorg. Chem.   2004, 43, 1587-1592  
107. Mayer, J.M.
Proton-Coupled Electron Transfer: A Reaction Chemist’s View,
Ann. Rev. Phys. Chem.   2004, 55, 363-390  
106. Mayer, J.M.; Rhile, I.J.
Thermodynamics and Kinetics of Proton-Coupled Electron Transfer: Stepwise vs. Concerted Pathways,
Biochem. Biophys. Acta   2004, 1655, 51-58  
105. Mayer, J.M.; Larsen, A.S.; Bryant, J.R.; Wang, K.; Lockwood, M.A.; Rice, G.; Won, T.-J.
Non-Organometallic Mechanisms for C-H Bond Oxidation: Hydrogen Atom vs. Electron vs. Hydride Transfer,
Adv. Chem. Ser., ‘Activation and Functionalization of C-H Bonds’   2004, 885, 356-369  
104. Soper, J.D.; Kaminsky, W.; Mayer, J.M.
Slow Hydrogen Atom Self-Exchange Between Os(IV) Anilide and Os(III) Aniline Complexes: Relationships with Electron and Proton Transfer Self Exchange,
J. Am. Chem. Soc.   2003, 125, 12217-12229  
103. Suzuki, T.; DiPasquale, A.G.; Mayer, J.M.
Nitrogen-Atom Insertion into Ir-S and C-S Bonds Initiated by Photolysis of Iridium(III)-Azido-Dithiocarbamato Complexes,
J. Am. Chem. Soc.   2003, 125, 10514-10515  
102. Bryant, J.R.; Mayer, J.M.
Oxidation of C-H Bonds by [(bpy)2(py)RuIVO]2+ Occurs by Hydrogen Atom Abstraction,
J. Am. Chem. Soc.   2003, 125, 10351-10361  
101. Bennett, B.K.; Saganic, E.; Lovell, S.; Kaminsky, W.; Samuel, A.; Mayer, J.M.
Osmium-Phosphiniminato Complexes: Synthesis, Protonation, Structure, and Redox-Coupled Hydrolytic Scission of N-P Bonds,
Inorg. Chem.   2003, 42, 4127-4134  
100. Yoder, J.C.; Roth, J.P.; Gussenhoven, E.M.; Larsen, A.S.; Mayer, J.M.
Electron and Hydrogen Atom Self-Exchange Reactions of Iron and Cobalt Coordination Complexes,
J. Am. Chem. Soc.   2003, 125, 2629-2640  
99. Dehestani, A.; Kaminsky, W.; Mayer, J.M.
Tuning the Properties of the Osmium Nitrido Group in TpOs(N)X2 by Changing the Ancillary Ligand,
Inorg. Chem.   2003, 42, 605-611  
98. DiPasquale, A.G.; Kaminsky, W.; Mayer, J.M.
Oxygen-Oxygen Bond Homolysis in a Novel Titanium(IV) Alkylperoxide Complex, Cp2Ti(OOtBu)Cl,
J. Am. Chem. Soc.   2002, 124, 14534-14535  
97. Mayer, J.M.; Hrovat, D.A.; Thomas, J.L.; Borden, W.T.
Proton-Coupled Electron Transfer vs. Hydrogen Atom Transfer in Benzyl/Toluene, Methoxyl/Methanol, and Phenoxyl/Phenol Self Exchange Reactions,
J. Am. Chem. Soc.   2002, 124, 11142-11147  
96. Larsen, A.S.; Wang, K.; Lockwood, M.A.; Rice, G.L.; Won, T.-J.; Lovell, S.; Sadílek, M.; Tureček, F.; Mayer, J.M.
Hydrocarbon Oxidation by Bis-μ-Oxo Manganese Dimers: Electron Transfer, Hydride Transfer, and Hydrogen Atom Transfer Mechanisms,
J. Am Chem. Soc.   2002, 124, 10112-10123  
95. Bryant, J.R.; Taves, J.E.; Mayer, J.M.
Oxidations of Hydrocarbons by Manganese(III) tris(hexafluoroacetylacetonate),
Inorg. Chem.   2002, 41, 2769-2776  
94. Roth, J.P.; Yoder, J.C.; Won, T.-J.; Mayer, J.M.
Application of the Marcus Cross Relation to Hydrogen Atom Transfer Reactions,
Science   2001, 294, 2524-2526  
93. Bennett, B.K.; Pitteri, S.; Pilobello, L.;§ Lovell, S.; Kaminsky, W., Mayer, J.M.
Osmium(IV) Complexes TpOs(X)Cl2 and Their Os(III) Counterparts: Oxidizing Compounds with an Unusual Resistance to Ligand Substitution,
J. Chem. Soc., Dalton Trans.   2001, , 3489-3497  
92. Soper, J.D.; Kaminsky, W.; Mayer, J.M.
Activation of an Anilido Ligand for Nucleophilic Aromatic Substitution by an Oxidizing Os(IV) Center,
J. Am. Chem. Soc.   2001, 123, 5594-5595  
91. Bennett, B.K.; Lovell, S.; Mayer, J.M.
Nitrogen Abstraction from Nitriles by Osmium(IV) Complexes,
J. Am. Chem. Soc.   2001, 123, 4336-4337  
90. Soper, J.D.; Bennett, B.K.; Lovell, S.; Mayer, J.M.
Protonation and Deprotonation of TpOs(NHPh)Cl2: An Unusually Inert Amido Ligand,
Inorg. Chem.   2001, 40, 1888-1893  
89. Crevier, T.J.; Bennett, B.K.; Soper, J.D.; Bowman, J.A.; Dehestani, A.; Hrovat, D.A.; Lovell, S.; Kaminski, W.; Mayer, J.M.
C-N Bond Formation on Addition of Aryl Carbanions to the Electrophilic Nitrido Ligand in TpOs(N)Cl2,
J. Am. Chem. Soc.   2001, 123, 1059-1071  
88. McCarthy, M.R.; Crevier, T.J.; Bennett, B.; Dehestani, A.; Mayer, J.M.
Nitric Oxide Abstracts a Nitrogen Atom from an Osmium Nitrido Complex to give Nitrous Oxide,
J. Am. Chem. Soc.   2000, 122, 12391-12392  
87. Matano, Y.; Northcutt, T.O.; Brugman, J.;§ Bennett, B.K.; Lovell, S.; Mayer, J.M.
Tp* Rhenium(V) Oxo-Halide, -Hydride, -Alkyl, -Phenyl, and –Alkoxide Complexes: Syntheses and Oxidations,
Organometallics  2000, 19, 2781-2790  
86. Roth, J.P.; Lovell, S.; Mayer, J.M.
Intrinsic Barriers for Electron and Hydrogen Atom Transfer Reactions of Biomimetic Iron Complexes,
J. Am. Chem. Soc.   2000, 122, 5486-5498  
85. Bennett, B.K.; Crevier, T.J.; DuMez, D.D.; Matano, Y.; McNeil, W.S.; Mayer, J.M.
Electrochemical and Reactivity Comparisons Among Isoelectronic Oxo, Imido, and Nitrido Complexes of Rhenium and Osmium,
J. Organomet. Chem.   1999, 591, 96-103  
84. Lockwood, M.A.; Wang, K.; Mayer, J.M.
Oxidation of Toluene by [(phen)2Mn(μ-O)2Mn(phen)2]4+ via Initial Hydride Abstraction,
J. Am. Chem. Soc.   1999, 121, 11894-11895  
83. McNeil, W.S.; DuMez, D.D.; Matano, Y.; Lovel, S.; Mayer, J.M.
Synthesis and Reactivity of Aryl-and Alkyl-Rhenium(V) Imido-Triflate Compounds: An Unusual Mechanism for Triflate Substitution,
Organometallics   1999, 18, 3715-3727  
82. DuMez, D.D.; Northcutt, T.O.; Matano, Y.; Mayer, J.M.
Fluoride Reactions with Hydrotris(pyrazolyl)borate Rhenium Oxo Complexes: Re-F vs. B-F Bond Formation,
Inorg. Chem.   1999, 38, 3309-3312  
81. Roth, J.P.; Mayer, J.M.
Hydrogen Transfer Reactivity of a Ferric Bi-imidazoline Complex that Models the Activity of Lipoxygenase Enzymes,
Inorg. Chem.   1999, 38, 2760-2761  

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